Advances in catalytic decarboxylation of bioderived fatty acids to diesel-range alkanes

被引:42
作者
Chen, Bi-Shuang [1 ]
Zeng, Yong-Yi [1 ]
Liu, Lan [1 ,2 ]
Chen, Lei [3 ]
Duan, Peigao [3 ]
Luque, Rafael [4 ,5 ]
Ge, Ran [6 ,7 ]
Zhang, Wuyuan [6 ,7 ]
机构
[1] Sun Yat Sen Univ, Sch Marine Sci, Zhuhai 519080, Peoples R China
[2] Southern Marine Sci & Engn Guangdong Lab Zhuhai, Zhuhai 519080, Peoples R China
[3] Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
[4] Univ Cordoba, Dept Quim Organ, Edificio Marie Curie C-3,Ctra Nnal 6-A,Km 396, E-14014 Cordoba, Spain
[5] Peoples Friendship Univ Russia, RUDN Univ, 6 Miklukho Maklaya Str, Moscow 117198, Russia
[6] Chinese Acad Sci, Tianjin Inst Ind Biotechnol, 32 West 7th Ave, Tianjin 300308, Peoples R China
[7] Natl Technol Innovat Ctr Synthet Biol, 32 West 7th Ave, Tianjin 300308, Peoples R China
关键词
Green diesel; Chemocatalysis; Enzymes; Decarboxylation; Renewable sources; Sustainability; BIODIESEL PRODUCTION; STEARIC-ACID; CARBOXYLIC-ACIDS; ENZYMATIC DECARBOXYLATION; ACETIC-ACID; TALL OIL; DEOXYGENATION; HYDROCARBONS; LIGHT; CARBON;
D O I
10.1016/j.rser.2022.112178
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Biodiesel is an important alternative fuel as far as sustainability and environmental issues are concerned. The decarboxylation of bioderived fatty acids is receiving great attention for green diesel production, with resulting C1-shortened alkanes among the diesel-range alkanes typically existing in petroleum diesel. Alkane-containing green diesel possesses significant advantages including high caloric value, irreversibility of the production reaction and the existence in liquid form up to C17 alkanes. The decarboxylation approach has a significant potential in taking a central role in transformation of bioderived fatty acids into green diesel. In the present review, it aims at discussing the progress on both chemo- and bio-catalytic decarboxylation reactions and the pros and cons of their application for green fuel synthesis. Particularly, the mild biocatalytic decarboxylation reactions so far have not been included in reviews focusing on green diesel production.
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页数:11
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