Early-late heterobimetallic Rh-Ti and Rh-Zr complexes via addition of early metal chlorides to mono- and divalent rhodium

被引：8

作者：

Smith, Dan A. ^{[1
]}

Ozerov, Oleg V. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 38期

基金：

美国国家科学基金会;

关键词：

SI-CL BONDS; OXIDATIVE ADDITION; (PNP)RH FRAGMENT; H BONDS; REACTIVITY; HALIDES; IRIDIUM; ELIMINATION; CO; PLATINUM(II);

D O I：

10.1039/c1cc14373e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of TiCl(4) or ZrCl(4) to (PNP)Rh(CH(2)=CH(t)Bu) (1) rapidly gives complexes (PNP)Rh(MCl(3))(Cl) (M = Ti, 2; Zr, 3) in 75-77% yield (PNP = (4-Me-2-((i)Pr(2)P)-C(6)H(3))(2)N). Compound 2 can also be synthesized via a reaction of (PNP)RhCl with TiCl(3) or of (PNP)TiCl(3) with 1/2 [(cod) RhCl](2).

引用

页码：10779 / 10781

页数：3

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