Aqua(diethylenetriamine)(isonicotinato)copper(II) hexafluorophosphate

被引：10

作者：

Nie, FM ^{[1
]}

Wang, ZM

Li, YM

Zhao, YF

Yan, CH

机构：

[1] Tsing Hua Univ, Dept Chem, Bioorgan Phosphorus Chem Lab, Beijing 100084, Peoples R China

[2] Beijing Univ, Dept Chem, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198010725

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Cu atom in the title complex, [N-(2-amino-ethyl-N)-1, 2-ethylenediamine -N,N'] aqua(4-pyridine-carboxylato -N)copper(II) hexafluorophosphate, [Cu(C6H4NO2)(C4H13N3)(H2O)]PF6, is coordinated in a square-pyramidal arrangement by three N atoms of N-(2-amino-ethyl)-1,2-ethylenediamine (diethylenetriamine) and one N atom from the pyridine ring of isonicotinate in equatorial positions, and by one water molecule in an axial position.

引用

页码：1853 / 1855

页数：3

共 10 条

[1]

*ENR, 1990, MOL STRUCT DET PACK

[2] ELECTRONIC PROPERTIES AND STEREOCHEMISTRY OF MONO-NUCLEAR COMPLEXES OF COPPER(II) ION [J].

HATHAWAY, BJ ;

BILLING, DE .

COORDINATION CHEMISTRY REVIEWS, 1970, 5 (02) :143-&

[3] (Diethylenetriamine)(imidazole)(thiocyanato)copper(II) perchlorate [J].

Hu, HM ;

Sun, HS ;

Chen, XH ;

Zhao, Q ;

Pan, Y ;

Huang, XY ;

You, XZ .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 :276-278

[4]

NONIUS BV, 1996, CAD 4 ARGUS SOFTWARE

[5] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[6] STRUCTURE OF THE COPPER(II) COMPLEX OF ISONICOTINIC-ACID [J].

OKABE, N ;

NAKAMURA, T ;

FUKUDA, H .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :1761-1762

[7] PREPARATION AND CRYSTAL-STRUCTURE OF AN IMIDAZOLATE-BRIDGED POLYNUCLEAR COMPLEX [(CU(IM)(DIEN))N][CIO4]N (DIEN = DIETHYLENETRIAMINE), AND ITS PROPERTIES IN DIMETHYLSULFOXIDE SOLUTION [J].

SATO, M ;

NAGAE, S ;

OHMAE, K ;

NAKAYA, J ;

MIKI, K ;

KASAI, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (09) :1949-1953

[8]

SHELDRICK GM, 1997, SHELXS97 PROGR SOL C

[9]

SHELDRICK GM, 1990, SHELXTL PC VERS 4 1

[10]

SHELDRICK GM, 1997, SHELXL97 PROGR REF C

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