Synthesis, crystal structure and standard molar enthalpy of formation of bis(trans-bis(N,N-dimethyl-(1-(R)-phenyl-2-(S)-methyl-2-aminoethoxy-N-O))-copper(II)) heptahydrate

被引：3

作者：

Dan, Wen-Yan ^{[1
]}

Chen, Jing-Tao ^{[2
]}

Di, You-Ying ^{[1
]}

Wang, Qiang ^{[1
]}

Yang, Wei-Wei ^{[1
]}

Kong, Yu-Xia ^{[1
]}

Wang, Da-Qi ^{[1
]}

机构：

[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China

[2] Shaanxi Educ Coll, Dept Chem, Xian 710061, Shaanxi Prov, Peoples R China

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2011年 / 43卷 / 02期

关键词：

Bis(trans-bis(N; N-dimethyl-(1-(R)-phenyl-2-(S)-methyl-2-aminoethoxy-N; O))-copper(II)); heptahydrate; Crystal structure; Isoperibol solution-reaction calorimeter; Standard molar enthalpy of formation; LANTHANIDE COMPLEXES; ANTICOAGULANT ACTION;

D O I：

10.1016/j.jct.2010.08.012

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A novel complex, bis(trans-bis(N,N-dimethyl-(1-(R)-phenyl-2-(S)-methyl-2-aminoethoxy-N,O))-copper(II)) heptahydrate (abbreviated as Cu-2(C11H16NO)(4)center dot 7H(2)O(cr)),was synthesized by the method of liquid phase reflux. The composition and structure of the complex were characterized by chemical analysis, elemental analysis. FUR, and X-ray crystallography. A reasonable thermochemical cycle was designed based on the preparation reaction of the coordination compound, and standard molar enthalpies of dissolution of reactants and products were measured by an isoperibol solution-reaction calorimeter. Finally, the standard molar enthalpy of formation of the complex Cu-2(C11H16NO)(4)center dot 7H(2)O(cr) was determined to be -(4525.22 +/- 13.71) kJ . mol(-1) in accordance with Hess's law. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：161 / 166

页数：6

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