Crystal Structure and Vibrational Spectra of [Ru(NH3)4(OH)(NO)] ZnCl4

被引：9

作者：

Chacon Villalba, M. E. ^{[1
]}

Echeverria, G. ^{[2
,3
]}

Aymonino, P. J. ^{[1
]}

Varetti, E. L. ^{[1
]}

机构：

[1] Univ Nacl La Plata, Fac Ciencias Exactas, Dept Quim, Ctr Quim Inorgan CEQUINOR CONICET UNLP, RA-1900 La Plata, Argentina

[2] Univ Nacl La Plata, Fac Ciencias Exactas, Dept Fis, RA-1900 La Plata, Argentina

[3] Univ Nacl La Plata, Fac Ciencias Exactas, Inst IFLP CONICET UNLP, RA-1900 La Plata, Argentina

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 04期

关键词：

Rutenium nitrosyl complex; ZnCl42-; anion; Structure; Infrared; Raman; Theoretical calculations; RAMAN-SPECTRA; REACTIVITY; LIGANDS; CATION; STATE; NO;

D O I：

10.1007/s10870-010-9910-8

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of [Ru(NH3)(4)(OH)(NO)]ZnCl4 was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational characteristics of the ZnCl4 (2-) anion.

引用

页码：508 / 513

页数：6

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