Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes

被引：126

作者：

Lee, Yong-Min ^{[1
]}

Kotani, Hiroaki ^{[2
]}

Suenobu, Tomoyoshi ^{[2
]}

Nam, Wonwoo ^{[1
]}

Fukuzumi, Shunichi ^{[2
]}

机构：

[1] Ewha Womans Univ, Dept Chem, Div Nano Sci, Ctr Biomimet Sci, Seoul 120750, South Korea

[2] Osaka Univ, Grad Sch Engn, Japan Sci & Technol Agcy, SORST,Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 02期

关键词：

D O I：

10.1021/ja077994e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron-transfer kinetics for the reduction of non-heme oxoiron(IV) complexes by a series of ferrocene derivatives were examined in deaerated acetonitrile, and the resulting data were evaluated in light of the Marcus theory of electron transfer to determine the reorganization energies of electron transfer and the one-electron reduction potentials of non-heme oxoiron(IV) complexes. The electron-transfer properties of non-heme oxoiron(IV) complexes are featured by the larger reorganization energies of electron transfer and the lower one-electron reduction potentials as compared with those of heme oxoiron(IV) complexes.

引用

页码：434 / +

页数：3

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