Novel electrochromic triphenylamine-based polyamides containing quinolin-8-yloxy group as probes for metal ions

被引：21

作者：

Cai, Wanan ^{[1
]}

Xiao, Tiandi ^{[1
]}

Niu, Haijun ^{[1
]}

Bai, Xuduo ^{[1
]}

Zhang, Yanhong ^{[1
]}

Wang, Cheng ^{[1
]}

Wang, Wen ^{[2
]}

Qi, Hong ^{[3
]}

机构：

[1] Heilongjiang Univ, Sch Chem Chem Engn & Mat, Dept Macromol Sci & Engn, Key Lab Funct Inorgan Mat Chem,Minist Educ, Harbin 150086, Heilongjiang, Peoples R China

[2] Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150080, Heilongjiang, Peoples R China

[3] Harbin Inst Technol, State Key Lab Urban Water Resource & Environm, Harbin 150090, Heilongjiang, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2017年 / 252卷

基金：

美国国家科学基金会;

关键词：

Polyamide; Triphenylamine; Electrochromic; Probe; FLUORESCENT CHEMOSENSORS; DELAYED FLUORESCENCE; AROMATIC POLYAMIDES; CU2+ IONS; SENSOR; POLYIMIDES; DERIVATIVES; COPPER(II); ACETONITRILE; HG2+;

D O I：

10.1016/j.snb.2017.06.022

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new series of soluble electrochromic polyamides (PAs) were synthesized from the reaction of 4,4'-diamino-4"-(quinolin-8-yloxy) triphenylamine (DAQTPA) with five dicarboxylic acid via direct poly condensation process, respectively. These amorphous materials showed the decomposition temperature at 5% weight loss was over 400 degrees C in N-2 atmosphere. The influence of aliphatic structure for spectroscopic properties of PA was measured by UV-vis and fluorescent (PL) spectroscopies and explained by the theory of the frontier molecular orbitals. It can be easily determined that DAQTPA performs the most strongly responsive to Cu2+ with obvious enhancement in UV-vis and quenching in PL profiles, which are completely different from the response of other metal ions. PAs also showed the exclusively selective response for Cu2+ in UV-vis spectra. A pair of obvious redox peaks was observed in the cyclic voltammetry (CV) test of PAs accompanied with the distinct color changed from original yellowish to green or blue. The PA bearing the pendent quinolin-8-yloxy performed as an electron-donating group was more stable in the electrochemical process. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：330 / 339

页数：10

共 56 条

[1] Quantitative self-powered electrochromic biosensors [J].

Aller Pellitero, Miguel ;

Guimera, Anton ;

Kitsara, Maria ;

Villa, Rosa ;

Rubio, Camille ;

Lakard, Boris ;

Doche, Marie-Laure ;

Hihn, Jean-Yves ;

Javier del Campo, F. .

CHEMICAL SCIENCE, 2017, 8 (03) :1995-2002

[2] A New Selective Chromogenic and Turn-On Fluorogenic Probe for Copper(II) in Water-Acetonitrile 1:1 Solution [J].

Ballesteros, Eduardo ;

Moreno, Daniel ;

Gomez, Teresa ;

Rodriguez, Teresa ;

Rojo, Josefa ;

Garcia-Valverde, Maria ;

Torroba, Tomas .

ORGANIC LETTERS, 2009, 11 (06) :1269-1272

[3] Introduction of a Fluorescent Probe to Amyloid-β to Reveal Kinetic Insights into Its Interactions with Copper(II) [J].

Branch, Thomas ;

Girvan, Paul ;

Barahona, Mauricio ;

Ying, Liming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (04) :1227-1230

[4] Near infrared electrochromic naphthalene-based polyimides containing triarylamine: Synthesis and electrochemical properties [J].

Cai, Jiwei ;

Ma, Lina ;

Niu, Haijun ;

Zhao, Ping ;

Lian, Yongfu ;

Wang, Wen .

ELECTROCHIMICA ACTA, 2013, 112 :59-67

[5] Multicolored near-infrared electrochromic polyimides: Synthesis, electrochemical, and electrochromic properties [J].

Cai, Jiwei ;

Niu, Haijun ;

Zhao, Ping ;

Ji, Yan ;

Ma, Lina ;

Wang, Cheng ;

Bai, Xuduo ;

Wang, Wen .

DYES AND PIGMENTS, 2013, 99 (03) :1124-1131

[6] Highly stable anodic green electrochromic aromatic polyamides: synthesis and electrochromic properties [J].

Chang, Cha-Wen ;

Liou, Guey-Sheng ;

Hsiao, Sheng-Huei .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (10) :1007-1015

[7] Novel Organosoluble Aromatic Polyimides Bearing Pendant Methoxy-Substituted Triphenylamine Moieties: Synthesis, Electrochromic, and Gas Separation Properties [J].

Chang, Cha-Wen ;

Yen, Hung-Ju ;

Huang, Kuan-Yeh ;

Yeh, Jui-Ming ;

Liou, Guey-Sheng .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (24) :7937-7949

[8] Generation and Spectroscopic Profiles of Stable Multiarylaminium Radical Cations Bridged by Fluorenes [J].

Chang, Chao-Che ;

Yueh, Han ;

Chen, Chao-Tsen .

ORGANIC LETTERS, 2011, 13 (10) :2702-2705

[9] Novel trends of electrochemical oxidation of amino-substituted triphenylamine derivatives [J].

Chiu, KY ;

Su, TX ;

Li, JH ;

Lin, TH ;

Liou, GS ;

Cheng, SH .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 575 (01) :95-101

[10] A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing [J].

Chou, Ho-Hsiu ;

Nguyen, Amanda ;

Chortos, Alex ;

To, John W. F. ;

Lu, Chien ;

Mei, Jianguo ;

Kurosawa, Tadanori ;

Bae, Won-Gyu ;

Tok, Jeffrey B. -H. ;

Bao, Zhenan .

NATURE COMMUNICATIONS, 2015, 6

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