Templated assembly of a μ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

被引：87

作者：

Andrews, Philip C. ^{[1
]}

Beck, Tobias

Forsyth, Craig M.

Fraser, Benjamin H.

Junk, Peter C.

Massi, Massimiliano

Roesky, Peter W.

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Univ Gottingen, Fak Chem, Gottingen, Germany

[3] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

DALTON TRANSACTIONS | 2007年 / 48期

关键词：

D O I：

10.1039/b710534g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.

引用

页码：5651 / 5654

页数：4

共 45 条

[41] Deviation from the planarity -: a large Dy3N cluster encapsulated in an Ih-C80 cage:: An X-ray crystallographic and vibrational spectroscopic study [J].

Yang, Shangfeng ;

Troyanov, Sergey I. ;

Popov, Alexey A. ;

Krause, Matthias ;

Dunsch, Lothar .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16733-16739

[42] THE STRUCTURES OF SOME RARE-EARTH BASIC NITRATES [LN6(MU-6-O)(MU-3-OH)8(H2O)12(NO3)6](NO3)2.XH2O, LN=Y, GD, YB, X(Y, YB)=4 X(GD)=5 - A NOVEL RARE-EARTH-METAL CLUSTER OF THE M6X8 TYPE WITH INTERSTITIAL O-ATOM [J].

ZAK, Z ;

UNFRIED, P ;

GIESTER, G .

JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 205 (1-2) :235-242

[43] {[Nd4(ox)4(NO3)2(OH)2(H2O)2]•5H2O}n:: A porous 3D lanthanide-based coordination polymer with a special luminescent property [J].

Zhang, Li-Zhi ;

Gu, Wen ;

Li, Bing ;

Liu, Xin ;

Liao, Dai-Zheng .

INORGANIC CHEMISTRY, 2007, 46 (03) :622-624

[44] Synthesis and characterization of two novel lanthanide coordination polymers with an open framework based on an unprecedented [Ln7(μ3-OH)8]13+ cluster [J].

Zheng, XJ ;

Jin, LP ;

Gao, S .

INORGANIC CHEMISTRY, 2004, 43 (05) :1600-1602

[45] Ligand-controlled self-assembly of polynuclear lanthanide-oxo/hydroxo complexes: from synthetic serendipity to rational supramolecular design [J].

Zheng, ZP .

CHEMICAL COMMUNICATIONS, 2001, (24) :2521-2529

← 1 2 3 4 5 →