Templated assembly of a μ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

被引：86
作者：
Andrews, Philip C. [1 ]
Beck, Tobias
Forsyth, Craig M.
Fraser, Benjamin H.
Junk, Peter C.
Massi, Massimiliano
Roesky, Peter W.
机构：
[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
[2] Univ Gottingen, Fak Chem, Gottingen, Germany
[3] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
来源：
DALTON TRANSACTIONS | 2007年 / 48期
关键词：
D O I：
10.1039/b710534g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.
引用
收藏
页码：5651 / 5654
页数：4
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