Templated assembly of a μ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

被引：87

作者：

Andrews, Philip C. ^{[1
]}

Beck, Tobias

Forsyth, Craig M.

Fraser, Benjamin H.

Junk, Peter C.

Massi, Massimiliano

Roesky, Peter W.

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Univ Gottingen, Fak Chem, Gottingen, Germany

[3] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

DALTON TRANSACTIONS | 2007年 / 48期

关键词：

D O I：

10.1039/b710534g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.

引用

页码：5651 / 5654

页数：4

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