Samarium(III) nitrate-catalyzed one-pot synthesis of 42-membered N,S,O-containing cyclophanes

被引：8
作者：
Makhmudiyarova, Nataliya N. [1 ]
Khatmullina, Guzeliya M. [1 ]
Meshcheryakova, Ekaterina S. [1 ]
Khalilov, Leonard M. [1 ]
Ibragimov, Askhat G. [1 ]
Dzhemilev, Usein M. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prospekt Oktyabrya, Ufa 450075, Russia
来源：
ARKIVOC | 2016年
基金：
俄罗斯基础研究基金会;
关键词：
Samarium(III) catalysis; cycloaminomethylation; 4,4 '-dimercaptodiphenyl oxide; N; N-bis(methoxymethyl)-N-arylamines; cyclophanes; macrocycles; MACROCYCLIC LIGANDS; SCHIFF-BASES; BORON MACROCYCLES; PYRIDINE; 1,9-BIS(5-FORMYLPYRROL-2-YL)DIPYRRINS; ALPHA,OMEGA-BIS-1,5,3-DITHIAZEPANES; CONSTRUCTION;
D O I：
10.3998/ark.5550190.p009.364
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An effective one-pot method for the synthesis of N-aryl-substituted 1,15,29-trioxa-6,10,20,24,34,38-hexathia-8,22,36-triaza[1.5.1.5.1.5]paracyclophanes by Sm(NO3)(3)center dot 6H(2)O-catalyzed heterocyclization of N,N-bis(methoxymethyl)-N-arylamines with 4,4'-dimercapto-diphenyl oxide has been developed. The structural features of the obtained N,S,O-containing cyclophanes have been studied.
引用
收藏
页码：48 / 57
页数：10
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