Simultaneous Determination of Hydroquinone, and Catechol Using a Multi-Walled Carbon Nanotube/GC Electrode Modified by Electrodeposition of Carbon Nanodots

被引:9
作者
Gu, Chunchuan [1 ]
Li, Xiaoping [2 ]
Liu, Hongying [2 ,3 ]
机构
[1] Hangzhou Canc Hosp, Dept Clin Lab, Hangzhou 310002, Zhejiang, Peoples R China
[2] Hangzhou Dianzi Univ, Coll Life Informat Sci & Instrument Engn, Hangzhou 310018, Zhejiang, Peoples R China
[3] Hangzhou Dianzi Univ, Key Lab Med Informat & Bioprinting Zhejiang Prov, Hangzhou 310018, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon nanotube; Carbon nanodot; Hydroquinone; Catechol; Biosensor; SIMULTANEOUS ELECTROCHEMICAL DETERMINATION; FILM-MODIFIED ELECTRODE; PASTE ELECTRODE; COMPOSITE FILM; ASCORBIC-ACID; URIC-ACID; GOLD NANOPARTICLES; BISPHENOL-A; GRAPHENE; RESORCINOL;
D O I
10.4028/www.scientific.net/JNanoR.54.42
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Herein, in order to detect hydroquinone (HQ) and catechol (CC) simultaneously, an electrochemical sensor with good selectivity and sensitivity was developed. It is constructed by electrodeposition of carbon nanodots (CDs) on the surface of multi-walled carbon nanotubes (MWNTs) doped glassy carbon electrode. First, the experimental parameter was optimized. The electrochemical behavior was then evaluated by electrochemical impedance spectroscopy and cyclic voltammetry. The linear range for HQ and CC was 0.1-200 mu M, and the detection limit was 0.03 mu M. Incorporated the large surface area and fast charge transfer of MWNTs and CDs with electrodeposition technology's stability, high excellent selectivity, sensitivity, stability and good reproducibility was exhibited by the fabricated sensor. Furthermore, the electrode was successfully used to determine the concentration of HQ and CC in tap water, and thus exhibited potential applications environment monitoring.
引用
收藏
页码:42 / 53
页数:12
相关论文
共 34 条
[1]   Fabrication of copper nanoparticles decorated multiwalled carbon nanotubes as a high performance electrochemical sensor for the detection of neotame [J].
Bathinapatla, Ayyappa ;
Kanchi, Suvardhan ;
Singh, Parvesh ;
Sabela, Myalowenkosi I. ;
Bisetty, Krishna .
BIOSENSORS & BIOELECTRONICS, 2015, 67 :200-207
[2]   Determination of polyphenols by high-performance liquid chromatography with inhibited chemiluminescence detection [J].
Cui, H ;
He, CX ;
Zhao, GW .
JOURNAL OF CHROMATOGRAPHY A, 1999, 855 (01) :171-179
[3]   Novel graphene flowers modified carbon fibers for simultaneous determination of ascorbic acid, dopamine and uric acid [J].
Du, Jiao ;
Yue, Ruirui ;
Ren, Fangfang ;
Yao, Zhangquan ;
Jiang, Fengxing ;
Yang, Ping ;
Du, Yukou .
BIOSENSORS & BIOELECTRONICS, 2014, 53 :220-224
[4]   A new electrochemical sensor based on Fe3O4 functionalized graphene oxide-gold nanoparticle composite film for simultaneous determination of catechol and hydroquinone [J].
Erogul, Seyma ;
Bas, Salih Zeki ;
Ozmen, Mustafa ;
Yildiz, Salih .
ELECTROCHIMICA ACTA, 2015, 186 :302-313
[5]   Voltammetric resolution of catechol and hydroquinone at eosin Y film modified carbon paste electrode [J].
Ganesh, P. S. ;
Swamy, B. E. Kumara .
JOURNAL OF MOLECULAR LIQUIDS, 2016, 220 :208-215
[6]   Simultaneous electroanalysis of hydroquinone and catechol at poly(brilliant blue) modified carbon paste electrode: A voltammetric study [J].
Ganesh, P. S. ;
Swamy, B. E. Kumara .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 756 :193-200
[7]   ZnO-CuxO/polypyrrole nanocomposite modified electrode for simultaneous determination of ascorbic acid, dopamine, and uric acid [J].
Ghanbari, Kh ;
Hajheidari, N. .
ANALYTICAL BIOCHEMISTRY, 2015, 473 :53-62
[8]   GC electrode modified with carbon nanotubes and NiO for the simultaneous determination of bisphenol A, hydroquinone and catechol [J].
Goulart, Lorena Athie ;
Mascaro, Lucia Helena .
ELECTROCHIMICA ACTA, 2016, 196 :48-55
[9]   One step synthesis cadmium sulphide/reduced graphene oxide sandwiched film modified electrode for simultaneous electrochemical determination of hydroquinone, catechol and resorcinol [J].
Hu, Shirong ;
Zhang, Wuxiang ;
Zheng, Jianzhong ;
Shi, Jiangu ;
Lin, Zhongqiu ;
Zhong, Ling ;
Cai, Guixiang ;
Wei, Chan ;
Zhang, Hanqiang ;
Hao, Aiyou .
RSC ADVANCES, 2015, 5 (24) :18615-18621
[10]   One-pot hydrothermal synthesis carbon nanocages-reduced graphene oxide composites for simultaneous electrochemical detection of catechol and hydroquinone [J].
Huang, Yi Hong ;
Chen, Jian Hua ;
Sun, Xue ;
Su, Zhen Bo ;
Xing, Hai Tao ;
Hu, Shi Rong ;
Weng, Wen ;
Guo, Hong Xu ;
Wu, Wen Bing ;
He, Ya San .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 212 :165-173