Accurate vibrational energy spectra and dissociation energies of some diatomic electronic states

被引:8
作者
Sun, Wei-guo [1 ]
Liu, Xiu-ying [1 ]
Wang, Yu-jie [1 ]
Zhan, Yan [1 ]
Fan, Qun-chao [1 ]
机构
[1] Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China
来源
FRONTIERS OF PHYSICS IN CHINA | 2008年 / 3卷 / 04期
基金
中国国家自然科学基金;
关键词
diatomic molecules; molecular ions; vibrational spectrum; dissociation energy; algebraic method;
D O I
10.1007/s11467-008-0032-0
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
An algebraic method (AM) used to study the full vibrational spectra of diatomic systems, and an analytical formula used to calculate accurate molecular dissociation energies are applied to study the full vibrational spectra and molecular dissociation energies of some electronic states of homonuclear and heteronuclear diatomic molecules and diatomic ions. Studies show that the AM method and the analytical expression are reliable and economical physical methods for studying full vibrational spectra and molecular dissociation energies of diatomic electronic systems theoretically. They are particularly useful for those diatomic systems whose high-lying vibrational energies may not be available.
引用
收藏
页码:382 / 413
页数:32
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