An effective formylation of adamantane with CO initiated by the aprotic organic superacid CBr4 center dot 2AlBr(3) under mild conditions

被引：16
作者：
Akhrem, I
Churilova, I
Bernadyuk, S
Volpin, M
机构：
[1] A.N.Nesmeyanov Inst. of O., Russian Academy of Science
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 32期
关键词：
D O I：
10.1016/0040-4039(96)01223-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of adamantane with carbon monoxide at -45 degrees divided by +20 degrees C over 0.5-2 h, catalyzed by the aprotic organic superacid CBr4 . 2AlBr(3), is described. The formylation of adamantane under CO atmosphere at 0 divided by +20 degrees C in the presence of methylcyclopentane as a source of hydride ion affords 1-adamantanecarbaldehyde (1) in yield 70-72% on adamantane for 1 h. Copyright (C) 1996 Elsevier Science Ltd.
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页码：5775 / 5778
页数：4
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