Iron-catalyzed aerobic oxidative functionalization of sp3 C-H bonds: a versatile strategy for the construction of N-heterocycles

被引：62

作者：

Chen, Xiuling ^{[1
]}

Chen, Tieqiao ^{[1
]}

Ji, Fangyan ^{[1
]}

Zhou, Yongbo ^{[1
]}

Yin, Shuang-Feng ^{[1
]}

机构：

[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2015年 / 5卷 / 04期

关键词：

EFFICIENT SYNTHESIS; PHENYLACETIC ACIDS; BENZYLIC OXIDATION; DECARBOXYLATION; OXYGENATION; ALKYLATION; METHYLENE; ARYLATION; KETONES; ETHERS;

D O I：

10.1039/c4cy01618a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Iron-catalyzed aerobic oxidative functionalization of sp(3) C-H bonds has been developed for the construction of N-heterocycles from easily available carboxylic acid derivatives and o-substituted anilines. This transformation represents a widely applicable protocol to N-heterocycles using biofriendly iron as a catalyst in combination with molecular oxygen or air as the sole oxidant.

引用

页码：2197 / 2202

页数：6

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