Gemini surfactants from alkyl glucosides.

被引：53

作者：

Castro, MJL ^{[1
]}

Kovensky, J ^{[1
]}

Cirelli, AF ^{[1
]}

机构：

[1] UNIV BUENOS AIRES,FAC CIENCIAS EXACTAS & NAT,DEPT QUIM ORGAN,CTR INVEST HIDRATOS CARBONO,CONICET,RA-1428 BUENOS AIRES,DF,ARGENTINA

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 23期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0040-4039(97)00817-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,5-Bis-[6-O-(n-butyl alpha-D-glucopyranosid)] glutarate 7 was synthesized starting from D-glucose by a simple procedure. The anomeric mixture of alkyl glucosides was separated by flash chromatography of their peracetates. Detritylation in neutral conditions is described. This is the first example of a non ionic gemini surfactant where alkyl glucosides are linked through a spacer at C-6. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：3995 / 3998

页数：4

相关论文

共 9 条

[1] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[2] SYNTHESIS OF NOVEL BIS(GLYCOSYL) ETHERS AS BOLAAMPHIPHILE SURFACTANTS [J].

GOUETH, P ;

RAMIZ, A ;

RONCO, G ;

MACKENZIE, G ;

VILLA, P .

CARBOHYDRATE RESEARCH, 1995, 266 (02) :171-189

[3] The regioselective synthesis of non-glycosidically linked oligosaccharides [J].

Grindley, TB ;

Namazi, H .

TETRAHEDRON LETTERS, 1996, 37 (07) :991-994

[4] MESOSTRUCTURE DESIGN WITH GEMINI SURFACTANTS - SUPERCAGE FORMATION IN A 3-DIMENSIONAL HEXAGONAL ARRAY [J].

HUO, QS ;

LEON, R ;

PETROFF, PM ;

STUCKY, GD .

SCIENCE, 1995, 268 (5215) :1324-1327

[5] SIMULATING THE SELF-ASSEMBLY OF GEMINI (DIMERIC) SURFACTANTS [J].

KARABORNI, S ;

ESSELINK, K ;

HILBERS, PAJ ;

SMIT, B ;

KARTHAUSER, J ;

VANOS, NM ;

ZANA, R .

SCIENCE, 1994, 266 (5183) :254-256

[6]

LORENZ K, 1984, CA, V101, P73052

[7] SURFACE-ACTIVITIES, BIODEGRADABILITY AND ANTIMICROBIAL PROPERTIES OF NORMAL-ALKYL GLUCOSIDES, MANNOSIDES AND GALACTOSIDES [J].

MATSUMURA, S ;

IMAI, K ;

YOSHIKAWA, S ;

KAWADA, K ;

UCHIBORI, T .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1990, 67 (12) :996-1001

[8] GEMINI SURFACTANTS - SYNTHESIS AND PROPERTIES [J].

MENGER, FM ;

LITTAU, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (04) :1451-1452

[9]

Schmidt RR, 1996, LIEBIGS ANN-RECL, P867