Excess enthalpy, excess volume, viscosity deviation, and speed of sound deviation for the mixture tetrahydrofuran+2,2,2-trifluoroethanol at (283.15, 298.15, and 313.15) K

被引：16

作者：

Pérez, E ^{[1
]}

Cardoso, M ^{[1
]}

Mainar, AM ^{[1
]}

Pardo, JI ^{[1
]}

Urieta, JS ^{[1
]}

机构：

[1] Univ Zaragoza, Fac Ciencias, GATHERS, Aragon Inst Engn Res I3A, E-50009 Zaragoza, Spain

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2003年 / 48卷 / 05期

关键词：

D O I：

10.1021/je034076x

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess enthalpies, densities, speeds of sound, and dynamic viscosities for the mixture tetrahydrofuran + 2,2,2-trifluoroethanol were measured at (283.15, 298.15, and 313.15) K. Excess volumes, deviations of the speed of sound, and deviations of the dynamic viscosity were calculated at the three temperatures. These properties with the excess enthalpies were graphically represented and fitted by Redlich-Kister equations.

引用

页码：1306 / 1309

页数：4

共 20 条

[1] Solvent effects on Diels-Alder reactions. The use of aqueous mixtures of fluorinated alcohols and the study of reactions of acrylonitrile [J].

Cativiela, C ;

Garcia, JI ;

Gil, J ;

Martinez, RM ;

Mayoral, JA ;

Salvatella, L ;

Urieta, JS ;

Mainar, AM ;

Abraham, MH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (03) :653-660

[2] FLUORINATED ALCOHOLS AS SOLVENTS FOR DIELS-ALDER REACTIONS OF CHIRAL ACRYLATES [J].

CATIVIELA, C ;

GARCIA, JI ;

MAYORAL, JA ;

ROYO, AJ ;

SALVATELLA, L .

TETRAHEDRON-ASYMMETRY, 1993, 4 (07) :1613-1618

[3] Solution structure of the p53 regulatory domain of the p19Arf tumor suppressor protein [J].

DiGiammarino, EL ;

Filippov, I ;

Weber, JD ;

Bothner, B ;

Kriwacki, RW .

BIOCHEMISTRY, 2001, 40 (08) :2379-2386

[4] PREDICTION OF DENSITY AND EXCESS VOLUME FOR THE TERNARY MIXTURE - (WATER PLUS 2,2,2-TRIFLUOROETHANOL PLUS 2,5,8,11,14-PENTAOXAPENTADECANE) FROM EXPERIMENTAL BINARY VALUES AT TEMPERATURES FROM 283.15 K TO 333.15 K [J].

ESTEVE, X ;

PATIL, KR ;

FERNANDEZ, J ;

CORONAS, A .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1995, 27 (03) :281-292

[5] Experimental and predicted viscosities of the binary system (n-hexane+1,3-dioxolane) and for the ternary system (n-hexane+1,3-dioxolane+1-butanol) at 298.15 and 313.15 K [J].

Gascón, I ;

Pardo, J ;

Santafé, J ;

Domínguez, M ;

Urieta, JS .

FLUID PHASE EQUILIBRIA, 2001, 180 (1-2) :211-220

[6] EXCESS VOLUMES OF MIXTURES OF OXOLANE, OXANE, 1,3-DIOXOLANE, AND 1,4-DIOXANE WITH NORMAL-ALKANES AT 298.15-K, 308.15-K, AND 318.15-K [J].

INGLESE, A ;

GROLIER, JPE ;

WILHELM, E .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1983, 28 (01) :124-127

[7] Flexibility and bioactivity of insulin: an NMR investigation of the solution structure and folding of an unusually flexible human insulin mutant with increased biological activity [J].

Keller, D ;

Clausen, R ;

Josefsen, K ;

Led, JJ .

BIOCHEMISTRY, 2001, 40 (35) :10732-10740

[8] THERMAL EXPANSIVITIES OF WATER + TETRAHYDROFURAN MIXTURES AT 298.15 K [J].

KIYOHARA, O ;

DARCY, PJ ;

BENSON, GC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (22) :2803-2807

[9] Excess molar enthalpies of cyclic ethers with cyclohexane, methylcyclohexane, or chlorocyclohexane [J].

Lafuente, C ;

Cea, P ;

Domínguez, M ;

Royo, FM ;

Urieta, JS .

JOURNAL OF SOLUTION CHEMISTRY, 2001, 30 (09) :795-805

[10]

Marsh K.N., 1987, Recommended Reference Materials for the Realization of Physicochemical Properties

← 1 2 →