Electrochemical intercalation of lithium into thin pyrocarbon layers

被引：0
|
作者：
Volgin, MA [1 ]
Churikov, AV [1 ]
Konoplyantseva, NA [1 ]
Gridina, NA [1 ]
L'vov, AL [1 ]
机构：
[1] Saratov State Univ, Saratov 410601, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 1998年 / 34卷 / 07期
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D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The intercalation of lithium from a 1 M LiClO4 solution in a mixture of propylene carbonate with dimethoxyethane into thin (below 1 mu m) carbon films is studied by chronopotentiometry, cyclic voltammetry, and X-ray diffractometry. The films are prepared by pyrolyzing toluene or methane on nickel or copper substrates. The influence exerted by the pyrolysis conditions on properties of pyrocarbon films and their electrochemical characteristics, the reversibility of the intercalation-deintercalation process, and the composition of the LiCx compounds that form in the process is discussed.
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页码：681 / 687
页数：7
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