Current Progress on the Chemical Modification of Carbon Nanotubes

被引：1047

作者：

Karousis, Nikolaos ^{[1
]}

Tagmatarchis, Nikos ^{[1
]}

Tasis, Dimitrios ^{[2
]}

机构：

[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[2] Univ Patras, Dept Mat Sci, Rion 26504, Greece

来源：

CHEMICAL REVIEWS | 2010年 / 110卷 / 09期

关键词：

COVALENT SIDEWALL FUNCTIONALIZATION; PHOTOINDUCED ELECTRON-TRANSFER; DIAMETER-SELECTIVE SOLUBILIZATION; DIELS-ALDER CYCLOADDITION; MRI CONTRAST AGENTS; IN-SITU SYNTHESIS; NONCOVALENT FUNCTIONALIZATION; METAL NANOPARTICLES; GOLD NANOPARTICLES; IONIC-LIQUID;

D O I：

10.1021/cr100018g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unique morphology and structure of carbon nanotubes (CNT) keep attracting a great number of researchers to explore the novel properties of these materials. Among various surface functionalization techniques, oxidation of CNTs is probably the most widely studied. Early treatment techniques involved gas-phase oxidation in air and oxidative plasmas. Carboxylated CNTs were extensively used as precursors for further covalent modification of CNTs, through esterification and/or amidation reactions. Moreover, a few other direct esterification/amidation procedures of oxidized CNTs were reported. In one of them, acid purified SWCNTs were treated with molten urea, which functions both as solvent and as reactant. Modification of CNTs with ionic liquids is expected to improve their compatibility and stability, enhancing the potential of CNTs in applications such as sensors and actuators, by improving the electrical contact with media.

引用

页码：5366 / 5397

页数：32

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