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Visible-light-driven electron donor-acceptor complex induced sulfonylation of diazonium salts with sulfinates
被引:37
|作者:
Liang, Xin
[1
]
Li, Yufei
[1
]
Xia, Qing
[1
]
Cheng, Lan
[1
]
Guo, Jianbo
[1
]
Zhang, Pei
[1
]
Zhang, Weihua
[1
]
Wang, Qingmin
[2
]
机构:
[1] Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Res Inst Elementoorgan Chem, Coll Chem,Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
基金:
中国国家自然科学基金;
关键词:
QUINOLINE N-OXIDES;
SULFUR-DIOXIDE;
PHOTOREDOX CATALYSIS;
EFFICIENT METHOD;
DUAL CATALYSIS;
BOND FORMATION;
ACID SALTS;
SULFONES;
ARYL;
OXIDATION;
D O I:
10.1039/d1gc03239a
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
This work reports an efficient sulfonylation reaction enabled by a visible-light-induced radical coupling reaction between phenyl/heterocyclic diazonium salts and sulfinates. Mechanistic experiments disclosed the formation of a versatile electron donor-acceptor (EDA) complex. This transformation is characterized by an easy operational procedure under mild conditions which avoids transition metals, ligands, catalysts, and oxidants.
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页码:8865 / 8870
页数:6
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