Visible-light-driven electron donor-acceptor complex induced sulfonylation of diazonium salts with sulfinates

被引:37
|
作者
Liang, Xin [1 ]
Li, Yufei [1 ]
Xia, Qing [1 ]
Cheng, Lan [1 ]
Guo, Jianbo [1 ]
Zhang, Pei [1 ]
Zhang, Weihua [1 ]
Wang, Qingmin [2 ]
机构
[1] Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Peoples R China
[2] Nankai Univ, State Key Lab Elementoorgan Chem, Res Inst Elementoorgan Chem, Coll Chem,Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
QUINOLINE N-OXIDES; SULFUR-DIOXIDE; PHOTOREDOX CATALYSIS; EFFICIENT METHOD; DUAL CATALYSIS; BOND FORMATION; ACID SALTS; SULFONES; ARYL; OXIDATION;
D O I
10.1039/d1gc03239a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work reports an efficient sulfonylation reaction enabled by a visible-light-induced radical coupling reaction between phenyl/heterocyclic diazonium salts and sulfinates. Mechanistic experiments disclosed the formation of a versatile electron donor-acceptor (EDA) complex. This transformation is characterized by an easy operational procedure under mild conditions which avoids transition metals, ligands, catalysts, and oxidants.
引用
收藏
页码:8865 / 8870
页数:6
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