Synthesis and characterization of cross-linked polymer from cardanol by solvent-free grinding polymerization

被引：34

作者：

Bai, Weibin ^{[1
]}

Xiao, Xueqing ^{[1
]}

Chen, Qinhui ^{[2
]}

Xu, Yanlian ^{[1
]}

Zheng, Sining ^{[1
]}

Lin, Jinhuo ^{[2
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

[2] Key Lab Polymer Mat, Fuzhou 350007, Peoples R China

来源：

PROGRESS IN ORGANIC COATINGS | 2012年 / 75卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Cardanol; Solvent-free grinding polymerization; Oxidative coupling reaction Friedel-Crafts reaction; Etherification reaction; NUT SHELL LIQUID; ENZYMATIC-SYNTHESIS; SOLID-STATE; PHENOLS; POLYURETHANES;

D O I：

10.1016/j.porgcoat.2012.04.016

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

By grinding cardanol and anhydrous FeCl3 powder using a glass pestle in a mortar at ambient and solvent-free condition, a novel cross-linked polymer from cardanol, a renewable resource, was synthesized in high yield up to 80% in 5 min. The products were characterized through UV-vis. FT-JR. and H-1 NMR; and the solvent-free grinding polymerization was consisted of Friedel-Crafts reaction, etherification reaction, and oxidative coupling reaction. The effect of these different techniques on spectral, thermal, optical, electrical, and morphological properties of polycardanol were investigated. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：184 / 189

页数：6

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