Ligands Entrapment in a 2D Parallel Stacked Co Complex with Mixed Ligands

被引：0

作者：

Qin, Ling ^{[1
,2
]}

Liu, Qing-He ^{[1
]}

Yang, Xi ^{[1
]}

Wang, Yan-Qing ^{[1
]}

机构：

[1] Hefei Univ Technol, Dept Chem Engn & Food Proc, Xuancheng Campus, Xuancheng 242000, Anhui, Peoples R China

[2] Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Jiangsu Engn Technol Res Ctr Environm Cleaning Ma, Nanjing, Jiangsu, Peoples R China

来源：

CRYSTALLOGRAPHY REPORTS | 2017年 / 62卷 / 07期

关键词：

METAL-ORGANIC FRAMEWORK; MOLECULES; NETWORK;

D O I：

10.1134/S106377451707015X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, {[Co-4(DPT)(4)(bdc)(4)] center dot DPT center dot DMF center dot H2O}(n) (1) was prepared under hydrothermal condition (dimethylformamide and water) based on mixed ligands, namely, 2,5-dipyridinethiophene (DPT) and 1,4-benzenedicarboxylate (H(2)bdc). DPT and bdc(2-) ligands link Co cations to give a 2D layer in the title complex. Each layer is stacked in parallel manners. The title compound has channels running in parallel to the a axis with the dimensions of 3.6 x 6.8 angstrom(2), which entraps a guest DPT ligand molecule.

引用

页码：1177 / 1181

页数：5

共 18 条

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