In-situ infrared thermographic analysis during dehydrogenation of cyclohexane over carbon-supported Pt catalysts using spray-pulsed reactor

被引:20
|
作者
Biniwale, RB
Yamashiro, H
Ichikawa, M [1 ]
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
[2] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
[3] Natl Environm Engn Res Inst, Nagpur 440020, Maharashtra, India
基金
日本学术振兴会;
关键词
IR thermography; cyclohexane dehydrogenation; hydrogen production; Pt catalyst; spray-pulse injection;
D O I
10.1007/s10562-005-5198-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Infrared thermography, a tool used for screening of active catalytic materials generally during the exothermic reactions has been used for thermal imaging during strong endothermic reaction of dehydrogenation of cyclohexane on Pt catalyst supported on active carbon cloth ( CFF- 1500s) sheets. A spray- pulsed mode was used for injection of atomized cyclohexane and to create alternate wet and dry condition on catalyst surface. The simultaneous product gas analysis and recording of the temperature pro. le of the catalyst surface using an IR camera was carried out. The production rate of hydrogen via endothermic dehydrogenation reaction is greatly dependent on the temperature of the catalyst surface. The observed change in the temperature pro. le at wet and dry conditions with varying pulse- injection frequency and corresponding product gas analysis reveals that the spray- pulse mode is useful in improving the catalyst activity. Further the reaction conditions were optimized using thermal pro. le data.
引用
收藏
页码:23 / 31
页数:9
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