Chiral Mn-salen catalyzed enantiotopic selective C-H oxidation of meso-pyrrolidine derivatives

被引:41
作者
Punniyamurthy, T [1 ]
Miyafuji, A [1 ]
Katsuki, T [1 ]
机构
[1] Kyushu Univ 33, Grad Sch Sci, Dept Mol Chem, Higashi Ku, Fukuoka 8128581, Japan
关键词
D O I
10.1016/S0040-4039(98)80001-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Asymmetric desymmetrization of meso-pyrrolidine derivatives was first effected by enantioselective oxidation of the C-H bond alpha to the nitrogen atom Mn-salen complex 1b as a catalyst. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8295 / 8298
页数:4
相关论文
共 16 条