Intriguing coordination behaviors of aquo and amine ligands bound to the organoruthenium(II) cation [Ru(eta(6)-C6H6)(bpop)](2+) (bpop=2,2-bis[4(R)-phenyl-1,3-oxazolon-2-yl]propane)

被引：34

作者：

Asano, H ^{[1
]}

Katayama, K ^{[1
]}

Kurosawa, H ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 20期

关键词：

D O I：

10.1021/ic960410h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dissociation of the Ru-O bond of coordinated water in the aquaruthenium complex 1 (L = H2O) was slower in acetone-db than in CD2Cl2, as evidenced by variable-temperature NMR experiments. The two N-hydrogens of the coordinated RNH(2) in the amine complex 4 (L = NH(2)Bu) underwent deuterium exchange in CD3OD with greatly different rates.

引用

页码：5760 / &

页数：3

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