Ruthenium-catalyzed addition of sulfenamides to alkynes leading to selective synthesis of polyfunctional alkenes

被引：26
|
作者：
Kondo, T [1 ]
Baba, A [1 ]
Nishi, Y [1 ]
Mitsudo, T [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 07期
基金：
日本学术振兴会;
关键词：
ruthenium catalyst; sulfenamide; alkyne; addition; polyfunctional alkene;
D O I：
10.1016/j.tetlet.2003.12.025
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sulfenamides smoothly add to alkynes by [RuCl2(CO)(3)](2) or Ru-3(CO)(12) catalyst to give the corresponding polyfunctional alkenes in high yield with high regio- and stereoselectivity (Z 100%). (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1469 / 1471
页数：3
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