Combustion of primary and secondary pulp mill sludge and their respective blends with coal: A thermogravimetric assessment

被引:50
作者
Coimbra, Ricardo N. [1 ]
Paniagua, Sergio [1 ]
Escapa, Carla [1 ]
Calvo, Luis F. [1 ]
Otero, Marta [1 ,2 ,3 ]
机构
[1] Univ Leon, IMARENABIO Inst Environm Nat Resources & Biodiver, Dept Appl Chem & Phys, E-24071 Leon, Spain
[2] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal
[3] Univ Aveiro, CESAM Ctr Environm & Marine Studies, P-3810193 Aveiro, Portugal
关键词
TGA/DSC analysis; Paper industry; Isoconversion model; Co-combustion; Vyazovkin; WASTE-WATER; KINETIC-ANALYSIS; SEWAGE-SLUDGE; PAPER SLUDGE; BIOMASS; ENERGY; COCOMBUSTION; TECHNOLOGIES; PYROLYSIS; BAGASSE;
D O I
10.1016/j.renene.2015.05.046
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Properties of primary and secondary pulp mill sludge are unalike and are also very different from those of coal. Thermogravimetric analysis was used to assess the separate combustion of coal, primary and secondary pulp mill sludge. Then, the co-combustion of coal with primary and with secondary pulp mill sludge was studied under identical experimental conditions. Both Differential Thermogravimetry burning profiles (DTG) and Differential Scanning Calorimetric analysis (DSC) showed remarkable differences between the combustion of coal, primary and secondary paper mill sludge. However, compared with the combustion of coal, the effects of adding a 10 wt.% of either primary or secondary paper mill sludge were not relevant in terms of weight loss or heat release. This was further proved by non-isothermal kinetic analysis, which was used to evaluate the apparent activation energy corresponding to the single combustions and to the co-combustion of blends. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1050 / 1058
页数:9
相关论文
共 40 条
[1]   Thermal and kinetic analyses of pure and oxidized bitumens [J].
Benbouzid, Mohammed ;
Hafsi, Said .
FUEL, 2008, 87 (8-9) :1585-1590
[2]   Waste-to-energy plant for paper industry sludges disposal: technical-economic study [J].
Caputo, AC ;
Pelagagge, PM .
JOURNAL OF HAZARDOUS MATERIALS, 2001, 81 (03) :265-283
[3]  
CEPI, 2013, KEY STAT 2013
[4]  
CEPI, 2013, CEPIS ONL SUST REP
[5]  
Elliott A., 2005, PULP PAP-CANADA, V79, P49
[6]   Pretreatment technologies for advancing anaerobic digestion of pulp and paper biotreatment residues [J].
Elliott, Allan ;
Mahmood, Talat .
WATER RESEARCH, 2007, 41 (19) :4273-4286
[7]   A QUICK DIRECT METHOD FOR DETERMINATION OF ACTIVATION ENERGY FROM THERMOGRAVIMETRIC DATA [J].
FLYNN, JH ;
WALL, LA .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1966, 4 (5PB) :323-&
[8]  
Friedman H.L., 1964, Journal of Polymer Science Part C: Polymer Symposia, V6, P183, DOI DOI 10.1002/POLC.5070060121
[9]  
Fu P.-f., 2013, CLEANER COMBUSTION S, P423
[10]   Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA) [J].
Idris, Siti Shawalliah ;
Rahman, Norazah Abd ;
Ismail, Khudzir .
BIORESOURCE TECHNOLOGY, 2012, 123 :581-591