Uranium-mediated activation of small molecules

被引：159

作者：

Arnold, Polly L. ^{[1
]}

机构：

[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 32期

关键词：

H BOND ACTIVATION; SANDWICH COMPLEXES; CARBON-MONOXIDE; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURE; TERMINAL ALKYNES; REACTIVITY; DINITROGEN; CHEMISTRY; COORDINATION;

D O I：

10.1039/c1cc10834d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular complexes of uranium are capable of activating a range of industrially and economically important small molecules such as CO, CO(2), and N(2); new and often unexpected reactions provide insight into an element that needs to be well-understood if future clean-energy solutions are to involve nuclear power.

引用

页码：9005 / 9010

页数：6

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