3D homometallic carboxylate ferrimagnet constructed from a Manganese(II) succinate carboxylate layer motif pillared by isonicotinate spacers

被引：93

作者：

Zeng, Ming-Hua ^{[1
]}

Wu, Mei-Chun

Liang, Hong

Zhou, Yan-Ling

Chen, Xiao-Ming

Ng, Seik-Weng

机构：

[1] GuangXi Normal Univ, Dept Chem & Chem Engn, Guilin 541004, Peoples R China

[2] Sun Yet Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synth Chem, Guangzhou 510275, Peoples R China

[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 18期

关键词：

D O I：

10.1021/ic700832w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A manganese succinate having a layer structure in which the layers are pillared by the isonicotinate spacers in a 3D architecture exhibits long-range ferrimagnetic order below 5.0 K, with the ferrimagnetism arising, for topological reasons, from the nature of the carboxylate binding modes. The compound is the first structurally authenticated example of a 3D ferrimagnet, featuring a homometallic topological ferrimagnetic sheet among metal carboxylates.

引用

页码：7241 / 7243

页数：3

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