Molecules composed of two weakly magnetically coupled [MnIII4] clusters

被引：48
作者：
Sanudo, E. Carolina
Cauchy, Thomas
Ruiz, Eliseo
Laye, Rebecca H.
Roubeau, Olivier
Teat, Simon J.
Aromi, Guillem
机构：
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] Univ Manchester, Manchester M13 9PL, Lancs, England
[3] Univ Bordeaux 1, Ctr Rech Paul Pascal, CNRS, F-33600 Pessac, France
[4] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 22期
关键词：
D O I：
10.1021/ic701467y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
With the help of a bis(beta-diketonate) ligand, a family of robust molecules is formed, all consisting of two [Mn(III)14] subunits that interact slightly magnetically with each other, through two bridging pyrazine ligands.
引用
收藏
页码：9045 / 9047
页数：3
相关论文
共 25 条
[1]   Linking rings through diamines and clusters: Exploring synthetic methods for making magnetic quantum gates [J].
Affronte, M ;
Casson, I ;
Evangelisti, M ;
Candini, A ;
Carretta, S ;
Muryn, C ;
Teat, SJ ;
Timco, GA ;
Wernsdorfer, W ;
Winpenny, REP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) :6496-6500
[2]   Bridging nitrate groups in [Mn4O3(NO3)(O2CMe)3(R2dbm)3] (R = H, Et) and [Mn4O2(NO3)(O2CEt)6(bpy)2](ClO4):: Acidolysis routes to tetranuclear manganese carboxylate complexes [J].
Aromi, G ;
Bhaduri, S ;
Artús, P ;
Folting, K ;
Christou, G .
INORGANIC CHEMISTRY, 2002, 41 (04) :805-817
[3]   A tetranuclear manganese carboxylate cluster with bis(2-pyridyl)amine ligation:: [Mn4O2(O2CEt)7(bpya)2](ClO4) [J].
Aromí, G ;
Bhaduri, S ;
Artús, P ;
Huffman, JC ;
Hendrickson, DN ;
Christou, G .
POLYHEDRON, 2002, 21 (18) :1779-1786
[4]  
Aromí G, 2002, ANGEW CHEM INT EDIT, V41, P1168, DOI 10.1002/1521-3773(20020402)41:7<1168::AID-ANIE1168>3.0.CO
[5]  
2-9
[6]  
Aromí G, 2001, ANGEW CHEM INT EDIT, V40, P3444, DOI 10.1002/1521-3773(20010917)40:18<3444::AID-ANIE3444>3.0.CO
[7]  
2-Q
[8]   Novel linear transition metal clusters of a heptadentate bis-β-diketone ligand [J].
Aromi, Guillem ;
Gamez, Patrick ;
Krzystek, J. ;
Kooijman, Huub ;
Spek, Anthony L. ;
MacLean, Elizabeth J. ;
Teat, Simon J. ;
Nowell, Harriott .
INORGANIC CHEMISTRY, 2007, 46 (07) :2519-2529
[9]   A zig-zag [MnII4] cluster from a novel bis(β-diketonate) ligand [J].
Aromi, Guillem ;
Gamez, Patrick ;
Boldron, Christophe ;
Kooijman, Huub ;
Spek, Anthony L. ;
Reedijk, Jan .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (10) :1940-1944
[10]   DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].
BECKE, AD .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652
123