Membership rules for a molecular box: The admission process and protection provided to guest molecules

被引：37

作者：

Hsu, SCN

Ramesh, M

Espenson, JH

Rauchfuss, TB ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[2] Iowa State Univ, Ames Lab, Dept Chem, Ames, IA 50011 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 23期

关键词：

cage compounds; cations; cobalt; cyanide; host-guest systems; ruthenium;

D O I：

10.1002/anie.200219562

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crate chemistry: The inclusion dynamics of molecular boxes has been studied by virtue of the synthesis of the voided ionophilic packing crate [{CpCo(CN)3}4-(Cp*Ru)4] (CP=C5H5 CP*=C5Me5). Numerous ions can then be inserted into the box (see scheme). The box exhibits the highest formation constant known for Cs+ ions. Once inside, ions are insulated from chemical attack, such as amine-deprotonation or H-D exchange.

引用

页码：2663 / 2666

页数：4

共 20 条

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