Two unprecedented NLO-active coordination polymers constructed by a semi-rigid tetrahedral linker

被引：50
作者：
Liang, Li-Li [1 ]
Ren, Shi-Bin [1 ]
Zhang, Jun [1 ]
Li, Yi-Zhi [1 ]
Du, Hong-Bin [1 ]
You, Xiao-Zeng [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 33期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; FERROELECTRIC PROPERTIES; ENHANCEMENT; NETWORKS; TOPOLOGY; DATABASE; COMPLEX; FILMS; NETS; SHG;
D O I：
10.1039/c0dt00255k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The assemblies of tetrahedral linker tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H4L) with ZnCl2 and CdBr2 yield two noncentrosymmetric, NLO-active coordination polymers [Zn-4(L-2)(H2O)(3)(DMA)]center dot 2H(2)O (1) and [Cd2L(DMA)(2)(H2O)(2)] (2), respectively. 1 has an unprecedented 2-fold interpenetrating sxa topology with ferroelectric properties, while 2 has a 7-fold interpenetrating dia network.
引用
收藏
页码：7723 / 7726
页数：4
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共 34 条
  • [11] Two-dimensional ferroelectric films
    Bune, AV
    Fridkin, VM
    Ducharme, S
    Blinov, LM
    Palto, SP
    Sorokin, AV
    Yudin, SG
    Zlatkin, A
    [J]. NATURE, 1998, 391 (6670) : 874 - 877
  • [12] Crystal engineering of NLO materials based on metal-organic coordination networks
    Evans, OR
    Lin, WB
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) : 511 - 522
  • [13] The first metal-organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties
    Fu, Da-Wei
    Zhang, Wen
    Xiong, Ren-Gen
    [J]. DALTON TRANSACTIONS, 2008, (30) : 3946 - 3948
  • [14] Dielectric anisotropy of a homochiral trinuclear nickel(II) complex
    Fu, Da-Wei
    Song, Yu-Mei
    Wang, Guo-Xi
    Ye, Qiong
    Xiong, Ren-Gen
    Akutagawa, Tomoyuki
    Nakamura, Takayoshi
    Chan, Philip Wai Hong
    Huang, Songping D.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (17) : 5346 - +
  • [15] A Multifunctional 3D Ferroelectric and NLO-Active Porous Metal-Organic Framework
    Guo, Zhengang
    Cao, Rong
    Wang, Xin
    Li, Hongfang
    Yuan, Wenbing
    Wang, Guojian
    Wu, Haohan
    Li, Jing
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) : 6894 - +
  • [16] Flexible eightfold interpenetrating channels: Selective binding with diamondoid network generating 1D organic guests
    Kim, H
    Suh, MP
    [J]. INORGANIC CHEMISTRY, 2005, 44 (04) : 810 - 812
  • [17] Flexible metal-organic supramolecular isomers for gas separation
    Kishan, Motkuri Radha
    Tian, Jian
    Thallapally, Praveen K.
    Fernandez, Carlos A.
    Dalgarno, Scott J.
    Warren, John E.
    McGrail, B. Peter
    Atwood, Jerry L.
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (04) : 538 - 540
  • [18] Strong polarization enhancement in asymmetric three-component ferroelectric superlattices
    Lee, HN
    Christen, HM
    Chisholm, MF
    Rouleau, CM
    Lowndes, DH
    [J]. NATURE, 2005, 433 (7024) : 395 - 399
  • [19] Ferroelectric Bi3.25La0.75Ti3O12 films of uniform a-axis orientation on silicon substrates
    Lee, HN
    Hesse, D
    Zakharov, N
    Gösele, U
    [J]. SCIENCE, 2002, 296 (5575) : 2006 - 2009
  • [20] Rational synthesis of a microporous metal-organic framework with PtS topology using a semi-rigid tetrahedral linker
    Liang, Li-Li
    Zhang, Jun
    Ren, Shi-Bin
    Ge, Gen-Wu
    Li, Yi-Zhi
    Du, Hong-Bin
    You, Xiao-Zeng
    [J]. CRYSTENGCOMM, 2010, 12 (07): : 2008 - 2010
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