Oxidative dehydrogenation of n-butane to n-butene and 1,3-butadiene over Mg3(VO4)2/MgO-ZrO2 catalysts: Effect of Mg:Zr ratio of support

被引：21

作者：

Lee, Jong Kwon ^{[1
]}

Lee, Howon ^{[1
]}

Hong, Ung Gi ^{[1
]}

Lee, Jinsuk ^{[2
]}

Cho, Young-Jin ^{[2
]}

Yoo, Yeonshick ^{[2
]}

Jang, Ho-Sik ^{[2
]}

Song, In Kyu ^{[1
]}

机构：

[1] Seoul Natl Univ, Inst Chem Proc, Sch Chem & Biol Engn, Seoul 151744, South Korea

[2] Samsung Total Petrochem Corp, Daesan 356711, South Korea

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2012年 / 18卷 / 03期

关键词：

Oxidative dehydrogenation; n-Butane; Oxygen capacity; Acidity; Vanadium-magnesium oxide; SELECTIVE OXIDATION; O CATALYSTS; PYROPHOSPHATE CATALYSTS; V/MGO CATALYSTS; CARBON-DIOXIDE; PERFORMANCE; PROPANE; GAMMA-BI2MOO6; BEHAVIOR; ALUMINA;

D O I：

10.1016/j.jiec.2011.12.011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MgO-ZrO2 supports with different Mg:Zr ratios (16:1, 8:1, 4:1, 2:1, and 1:1) were prepared by a geloxalate co-precipitation method, and Mg-3(VO4)(2)/MgO-ZrO2 catalysts were then prepared by a wet impregnation method. The prepared catalysts were applied to the oxidative dehydrogenation of n-butane to n-butene and 1,3-butadiene. Experimental results revealed that oxygen capacity and acidity of the catalyst were closely related to the catalytic performance. Among the catalyst tested, Mg-3(VO4)(2)/MgO-ZrO2 (4:1) catalyst, which retained the largest oxygen capacity and acidity, exhibited the best catalytic performance in the oxidative dehydrogenation of n-butane. (C) 2011 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：1096 / 1101

页数：6

共 44 条

[1] Key aspects of catalyst design for the selective oxidation of paraffins [J].

Albonetti, S ;

Cavani, F ;

Trifiro, F .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1996, 38 (04) :413-438

[2] Oxidative dehydrogenation of butane on V/MgO catalytic membranes [J].

Alfonso, MJ ;

Menéndez, M ;

Santamaría, J .

CHEMICAL ENGINEERING JOURNAL, 2002, 90 (1-2) :131-138

[3] OXIDATIVE DEHYDROGENATION OF N-BUTANE ON IRON-ZINC OXIDE CATALYSTS [J].

ARMENDARIZ, H ;

AGUILARRIOS, G ;

SALAS, P ;

VALENZUELA, MA ;

SCHIFTER, I ;

ARRIOLA, H ;

NAVA, N .

APPLIED CATALYSIS A-GENERAL, 1992, 92 (01) :29-38

[4] Influence of the acid-base character of supported vanadium catalysts on their catalytic properties for the oxidative dehydrogenation of n-butane [J].

Blasco, T ;

Nieto, JML ;

Dejoz, A ;

Vazquez, MI .

JOURNAL OF CATALYSIS, 1995, 157 (02) :271-282

[5] Performance of PtSn catalysts supported on MAl2O4 (M: Mg or Zn) in n-butane dehydrogenation:: characterization of the metallic phase [J].

Bocanegra, SA ;

Guerrero-Ruiz, A ;

de Miguel, SR ;

Scelza, OA .

APPLIED CATALYSIS A-GENERAL, 2004, 277 (1-2) :11-22

[6] Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts [J].

Bocanegra, Sonia A. ;

Castro, Alberto A. ;

Scelza, Osvaldo A. ;

de Miguel, Sergio R. .

APPLIED CATALYSIS A-GENERAL, 2007, 333 (01) :49-56

[7] Behavior of bimetallic PtSn/Al2O3 catalysts prepared by controlled surface reactions in the selective dehydrogenation of butane [J].

Bocanegra, Sonia A. ;

de Miguel, Sergio R. ;

Borbath, Irina ;

Margitfalvi, Jozsef L. ;

Scelza, Osvaldo A. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 301 (1-2) :52-60

[8] Structural characterisation of a VMgO catalyst used in the oxidative dehydrogenation of propane [J].

Burrows, A ;

Kiely, CJ ;

Perregaard, J ;

Hojlund-Nielsen, PE ;

Vorbeck, G ;

Calvino, JJ ;

López-Cartes, C .

CATALYSIS LETTERS, 1999, 57 (03) :121-128

[9] On the role of acidity in catalytic oxidation [J].

Busca, G ;

Finocchio, E ;

Ramis, G ;

Ricchiardi, G .

CATALYSIS TODAY, 1996, 32 (1-4) :133-143

[10] SELECTIVE OXIDATIVE DEHYDROGENATION OF BUTANE OVER V-MG-O CATALYSTS [J].

CHAAR, MA ;

PATEL, D ;

KUNG, MC ;

KUNG, HH .

JOURNAL OF CATALYSIS, 1987, 105 (02) :483-498

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