New perfluoroalkylated cinchona derivatives: synthesis and use in base-catalysed Diels-Alder reactions

被引：51

作者：

Fache, F ^{[1
]}

Piva, O ^{[1
]}

机构：

[1] Univ Lyon 1, Lab Chim Organ Photochim & Synth, CNRS, UMR 5622, F-69622 Villeurbanne, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 33期

关键词：

perfluorinated ligands; alkaloids; asymmetric catalysis; base-catalysed reactions; Diels-Alder reactions;

D O I：

10.1016/S0040-4039(01)01036-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluorinated cinchona derivatives 1-4 were synthesised starting from commercially available compounds. They were tested in fluorous solvents in base catalysed Diels-Alder reactions and delivered adducts with ee up to 40% (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：5655 / 5657

页数：3

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