A route to microporous materials through oxidative pillaring of micas

被引：34

作者：

Baumgartner, Alexander ^{[1
]}

Sattler, Katrin ^{[1
]}

Thun, Juergen ^{[1
]}

Breu, Josef ^{[1
]}

机构：

[1] Univ Bayreuth, Lehrstuhl Anorgan Chem 1, D-95447 Bayreuth, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 09期

关键词：

intercalations; layered compounds; microporous materials; silicates;

D O I：

10.1002/anie.200704790

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Oxidative pillaring: The intercalation of a molecular pillar (Me2DABCO2+) into synthetic Cs-tainiolite, which shows sufficient intracrystalline reactivity by an oxidative cation-exchange mechanism, yields a material with microporosity that resembles zeolites in both narrow pore size distribution and total pore volume. Owing to the high structural Fe content, this pillared clay provides a size-selective, shape-selective, and electronically conducting framework. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1640 / 1644

页数：5

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