Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries

被引:233
作者
Yasin, Ghulam [1 ,2 ]
Arif, Muhammad [2 ]
Mehtab, Tahira [3 ]
Lu, Xia [1 ,4 ]
Yu, Donglin [1 ]
Muhammad, Noor [5 ]
Nazir, M. Tariq [6 ]
Song, Huaihe [5 ]
机构
[1] Beijing Univ Chem Technol, CWRU Int Joint Lab, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Coll Energy,State Key Lab Organ Inorgan Composite, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[3] Islamia Univ Bahawalpur, Dept Phys, Bahawalpur 63100, Pakistan
[4] Sun Yat Sen Univ, Sch Mat, Guangzhou 510275, Peoples R China
[5] Beijing Univ Chem Technol, Coll Mat Sci & Engn, State Key Lab Chem Resource Engn, Lab Adv Carbon Mat Res, Beijing 100029, Peoples R China
[6] Univ New South Wales, Sch Mech & Mfg Engn, Sydney, NSW 2052, Australia
基金
中国国家自然科学基金;
关键词
Li anode; Dendrites; Suppression strategies; Lithium metal batteries; SOLID-ELECTROLYTE INTERPHASE; RAY PHOTOELECTRON-SPECTROSCOPY; CU CURRENT COLLECTOR; DENDRITE-FREE; HIGH-ENERGY; IN-SITU; HIGH-PERFORMANCE; IONIC LIQUID; ELECTROCHEMICAL-BEHAVIOR; POLYMER ELECTROLYTES;
D O I
10.1016/j.ensm.2019.09.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, the technology of lithium metal-based batteries has devoted substantial importance with suggesting the great potential for power sources that could promise the revolution of electric vehicle (EV) and power grid. It is expected to overcome the challenges and barriers experienced during the use of these high energy density batteries in the desired large-scale applications such as hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV) and pure electric vehicle (PEV). Apart from the high energy density and enormous applications of Li-ion batteries, still there are some issues affecting the rate capability, performance, safety and cost due to dendritic growth during cycling of lithium batteries. Therefore, it is generous worthy to provide existing and timely apprises of constantly improving techniques to diminish the dendrites formation, especially for the metallic Li anode, because dendritic growth is the main problem that inhibits the commercial applications of lithium metal batteries in regular portable electronics to EV. In this review, we concisely summarize the fundamentals, existing issues, solid electrolyte interphases (SEI) on lithium metal anode, insight understanding and growth of dendritic structure and morphologies. Moreover, different prevention techniques for dendrites suppression, and some significant remarks are provided for future research and development of advanced dendrite free Li metal batteries for safe and potential use in the electric vehicles and also in high load-leveling applications.
引用
收藏
页码:644 / 678
页数:35
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