Preparation and crystal structure determination of Eu27Ti20X2S54O12 (X≈I0.35Cl0.65)

被引：3

作者：

Cario, L ^{[1
]}

Cody, JA ^{[1
]}

Deudon, C ^{[1
]}

Meerschaut, A ^{[1
]}

机构：

[1] Inst Mat Nantes, CNRS, UMR 110, Lab Chim Solides, F-44322 Nantes 03, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1998年 / 1卷 / 02期

关键词：

oxysulfure; europium; titane;

D O I：

10.1016/S1251-8069(97)86270-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the new compound Eu27Ti20X2S54O12 (X approximate to I-0.35 Cl-0.65), prepared by solid state (2)(not congruent to) [(Ti4S2O4)(Ti2S10)(4/2)] planes built up from rutile-like chains that cross perpendicularly. reaction, contains Two [TiS6] octahedra separate the [Ti4S2O4] clusters at the chain intersections. These planes are separated by a corrugated layer of [Ti3S8O4] triplets of fare-sharing Ti-centered octahedra. Five crystallographically independent europium ions are seven-to nine-coordinated. (C) Academie des Sciences/Elsevier, Paris.

引用

页码：115 / 121

页数：7

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