Preparation and Characterization of Polyacrylonitrile-Metal-O-MMT Nanocomposites

被引：0
作者：
Feng Huixia [1 ,2 ]
Fu Gongwei [2 ]
Wang Yi [1 ,2 ]
Chen Nali [1 ]
Yang Ruichen [2 ]
机构：
[1] Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
[2] Lanzhou Univ Technol, Coll Mat Sci & Engn, Lanzhou 730050, Peoples R China
来源：
ADVANCED POLYMER SCIENCE AND ENGINEERING | 2011年 / 221卷
关键词：
Polyacrylonitrile; montmorillonite; nanoconnposites; interlayer; THERMAL/MECHANICAL PROPERTIES;
D O I：
10.4028/www.scientific.net/AMR.221.316
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polyacrylonitrile-metal-O-montmorillonite nanocomposites were prepared by means of in situ polymerization. The Na-montmorillonite was modified by quaternary ammonium salt after the exchange of its interlayer cations with Ni2+. Infrared spectra and X-ray powder diffraction were employed to characterize the obtained polyacrylonitrile-metal-O-montmorillonite. The results of FTIR show that metal-O-montmorillonite has been concerned with the polymerization of PAN. The result of X-ray powder diffraction shows that the inserting of the acrylonitrile monomer can enlarge the interlayer space of montmorillonite. It is also shown that the polyacrylonitrile-metal-O-montmorillonite nanocomposites have been synthesized. The thermal stability of PAN /MMT is better than that of pure PAN.
引用
收藏
页码：316 / +
页数：2
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