Structure and Dynamics of Reentrant Nematics: Any Open Questions after Almost 40 Years?

被引:17
作者
Mazza, Marco G. [1 ]
Schoen, Martin [1 ,2 ]
机构
[1] Berlin Inst Technol, Stranski Lab Phys & Theoret Chem, D-10623 Berlin, Germany
[2] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA
关键词
reentrant phase; nematic; dynamics; diffusion; MOLEKULAR-STATISTISCHE THEORIE; PROTON SPIN RELAXATION; LIQUID-CRYSTAL; X-RAY; MOLECULAR-DYNAMICS; SMECTIC-AD; GAS MODEL; PHASE; NMR; BEHAVIOR;
D O I
10.3390/ijms12085352
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Liquid crystals have attracted enormous interest because of the variety of their phases and richness of their application. The interplay of general physical symmetries and specific molecular features generates a myriad of different phenomena. A surprising behavior of liquid crystals is the reentrancy of phases as temperature, pressure, or concentration are varied. Here, we review the main experimental facts and the different theoretical scenarios that have guided the understanding of bulk reentrant nematics. Recently, some computer simulations of a system confined to nanoscopic scales have found new dynamical features of the reentrant nematic phase. We discuss this prediction in relation with the available experimental evidence on reentrant nematics and with the dynamics of liquids in strongly confined environments.
引用
收藏
页码:5352 / 5372
页数:21
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