Precise Synthesis of Amphiphilic Multiblock Copolymers by Combination of Acyclic Diene Metathesis (ADMET) Polymerization with Atom Transfer Radical Polymerization (ATRP) and Click Chemistry

被引：42

作者：

Abdellatif, Mohamed Mehawed ^{[1
]}

Nomura, Kotohiro ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Dept Chem, Fac Sci & Engn, Hachioji, Tokyo 1920397, Japan

来源：

ACS MACRO LETTERS | 2012年 / 1卷 / 03期

关键词：

ALTERNATING BLOCK-COPOLYMERS; CONJUGATED POLYMERS; POLY(ETHYLENE GLYCOL); DEFINED LENGTH; DEFECT-FREE; PHOTOPHYSICS; POLY(MACROMONOMER)S; ELECTROLUMINESCENCE; DERIVATIVES; MOLYBDENUM;

D O I：

10.1021/mz300061a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various block (graft) copolymers have been prepared by combination of acyclic diene metathesis (ADMET) polymerization of 9,9-dialky1-2,7-divinyl-fluorene with Cu-catalyzed atom transfer radical polymerization (ATRP) of styrene using macroinitiators prepared by introduction of initiating functionalities vinylene)s (PFVs) chain ends: a precise synthesis of the amphiphilic ABCBA-type into ends: block poly(9,9-dialkylfluorene-2,7-vinylene)s (PFVs) chain ends: a precise synthesis of the copolymers has also been attained by subsequent combination with click reaction after modification of the chain end with NaN3.

引用

页码：423 / 427

页数：5

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