Precise Synthesis of Amphiphilic Multiblock Copolymers by Combination of Acyclic Diene Metathesis (ADMET) Polymerization with Atom Transfer Radical Polymerization (ATRP) and Click Chemistry

被引：42
|
作者：
Abdellatif, Mohamed Mehawed [1 ]
Nomura, Kotohiro [1 ]
机构：
[1] Tokyo Metropolitan Univ, Dept Chem, Fac Sci & Engn, Hachioji, Tokyo 1920397, Japan
来源：
ACS MACRO LETTERS | 2012年 / 1卷 / 03期
关键词：
ALTERNATING BLOCK-COPOLYMERS; CONJUGATED POLYMERS; POLY(ETHYLENE GLYCOL); DEFINED LENGTH; DEFECT-FREE; PHOTOPHYSICS; POLY(MACROMONOMER)S; ELECTROLUMINESCENCE; DERIVATIVES; MOLYBDENUM;
D O I：
10.1021/mz300061a
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Various block (graft) copolymers have been prepared by combination of acyclic diene metathesis (ADMET) polymerization of 9,9-dialky1-2,7-divinyl-fluorene with Cu-catalyzed atom transfer radical polymerization (ATRP) of styrene using macroinitiators prepared by introduction of initiating functionalities vinylene)s (PFVs) chain ends: a precise synthesis of the amphiphilic ABCBA-type into ends: block poly(9,9-dialkylfluorene-2,7-vinylene)s (PFVs) chain ends: a precise synthesis of the copolymers has also been attained by subsequent combination with click reaction after modification of the chain end with NaN3.
引用
收藏
页码：423 / 427
页数：5
相关论文
共 50 条
  • [31] Synthesis of poly(cyclohexene oxide)-block-polystyrene by combination of radical-promoted cationic polymerization, atom transfer radical polymerization and click chemistry
    Degirmenci, Mustafa
    Genli, Nasrettin
    POLYMER INTERNATIONAL, 2010, 59 (06) : 859 - 866
  • [32] Graft copolymers prepared by atom transfer radical polymerization (ATRP) from cellulose
    Meng, Tao
    Gao, Xia
    Zhang, Jun
    Yuan, Jinying
    Zhang, Yuzhu
    He, Jiasong
    POLYMER, 2009, 50 (02) : 447 - 454
  • [33] Sequence-regulated vinyl polymers via iterative atom transfer radical additions and acyclic diene metathesis polymerization
    Miyajima, Masato
    Satoh, Kotaro
    Kamigaito, Masami
    POLYMER CHEMISTRY, 2021, 12 (03) : 423 - 431
  • [34] Biodegradable amphiphilic graft polymer synthesized via the combination of ring-opening polymerization (ROP) and atom transfer radical polymerization (ATRP)
    Zhang, Xiaojin
    Wang, Hongquan
    Dai, Yu
    MATERIALS LETTERS, 2017, 198 : 144 - 147
  • [35] Acyclic Diene Metathesis (ADMET) Polymerization for Precise Synthesis of Defect-Free Conjugated Polymers with Well-Defined Chain Ends
    Haque, Tahmina
    Nomura, Kotohiro
    CATALYSTS, 2015, 5 (02) : 500 - 517
  • [36] Acyclic Diene Metathesis (ADMET) Polymerization for the Synthesis of Chemically Recyclable Bio-Based Aliphatic Polyesters
    Nomura, Kotohiro
    Wang, Xiuxiu
    CATALYSTS, 2024, 14 (02)
  • [37] Synthesis of a (sic)-shaped amphiphilic block copolymer by the combination of atom transfer radical polymerization and living anionic polymerization
    Yu, Xifei
    Shi, Tongfei
    An, Lijia
    Zhang, Guo
    Dutta, P. K.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (01) : 147 - 156
  • [38] Combination of atom transfer radical polymerization and click chemistry toward cellulose-rosin derived UV-absorbent copolymers
    Lu, Chuanwei
    Qiu, Yuling
    Guo, Xiaoliang
    Wang, Chunpeng
    Wang, Jifu
    Chu, Fuxiang
    IRANIAN POLYMER JOURNAL, 2020, 29 (11) : 975 - 983
  • [39] Combination of atom transfer radical polymerization and click chemistry toward cellulose-rosin derived UV-absorbent copolymers
    Chuanwei Lu
    Yuling Qiu
    Xiaoliang Guo
    Chunpeng Wang
    Jifu Wang
    Fuxiang Chu
    Iranian Polymer Journal, 2020, 29 : 975 - 983
  • [40] Amphiphilic block copolymers via acyclic diene metathesis polymerization: one-step synthesis, characterization, and self-assembly
    Liang Ding
    Xueqin Zheng
    Jing An
    Jun Qiu
    Rong Lu
    Journal of Polymer Research, 2013, 20
12345