The Equilibrium Constant for Bromothymol Blue: A General Chemistry Laboratory Experiment Using Spectroscopy

被引:42
作者
Klotz, Elsbeth [1 ]
Doyle, Robert [1 ]
Gross, Erin [1 ]
Mattson, Bruce [1 ]
机构
[1] Creighton Univ, Dept Chem, Omaha, NE 68178 USA
关键词
First-Year Undergraduate/General; Laboratory Instruction; Hands-On Learning / Manipulatives; Acids/Bases; Equilibrium; Green Chemistry; Physical Chemistry; Dyes/Pigments; UV-Vis Spectroscopy;
D O I
10.1021/ed1007102
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, inexpensive, and environmentally friendly undergraduate laboratory experiment is described in which students use visible spectroscopy to determine a numerical value for an equilibrium constant, K-c. The experiment correlates well with the lecture topic of equilibrium even though the subject of the study is an acid-base indicator, bromothymol blue. The experiment gives excellent results and offers an inexpensive, zero-waste alternative to traditional equilibrium experiments, such as the Fe(SCN)(2+) equilibrium.
引用
收藏
页码:637 / 639
页数:3
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