Dielectric and magnetic properties of BiFeO3 ceramics prepared by hydrothermal synthesis

被引:25
作者
Kim, A. Y. [2 ]
Han, S. H. [3 ]
Kang, H-W. [3 ]
Lee, H-G. [3 ]
Kim, J. S. [2 ]
Cheon, C. I. [1 ,2 ]
机构
[1] Hoseo Univ, Dept Mat Sci & Engn, Asan 336795, Chungnam, South Korea
[2] Hoseo Univ, Dept Semicond & Display Engn, Asan 336795, Chungnam, South Korea
[3] Korea Elect Technol Inst, Elect Mat & Device Res Ctr, Songnam 463816, Kyeonggi, South Korea
关键词
Powders: chemical preparation; Sintering; Dielectric properies; Magnetic properties; MULTIFERROIC BIFEO3; BISMUTH FERRITE; TEMPERATURE; POLARIZATION;
D O I
10.1016/j.ceramint.2011.05.019
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Single-phase BiFeO3 powders were prepared at a temperature of 200 degrees C by a hydrothermal synthesis. BiFeO3 ceramics were prepared with the powders by a conventional ceramic process. The BiFeO3 ceramics with no impurity phase were prepared at the sintering temperature of 650-800 degrees C. The dense microstructure was observed in the BiFeO3 ceramics sintered at a temperature of 700 degrees C and higher. BiFeO3 ceramics show linear M H curves in low H, which are antiferromagnetic behaviors. The dielectric dispersion was observed at the frequency range of 10 kHz to 1 MHz in the BiFeO3 ceramic sintered at 700 degrees C or lower. The dielectric constant and loss of the BiFeO3 ceramics sintered at 750 degrees C or higher were about 85 and 0.4 at 100 kHz, respectively. (C) 2011 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:S397 / S401
页数:5
相关论文
共 17 条
[1]   PREPARATION OF SINGLE-PHASE POLYCRYSTALLINE BIFEO3 [J].
ACHENBACH, GD ;
JAMES, WJ ;
GERSON, R .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (08) :437-+
[2]  
Chen C, 2006, J CRYST GROWTH, V291, P135, DOI 10.1016/j.jcrysgro.2006.02.048
[3]   Structure, ferroelectric properties, and magnetic properties of the La-doped bismuth ferrite [J].
Cheng, Z. X. ;
Li, A. H. ;
Wang, X. L. ;
Dou, S. X. ;
Ozawa, K. ;
Kimura, H. ;
Zhang, S. J. ;
Shrout, T. R. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (07)
[4]   Low-Temperature Hydrothermal Synthesis of Pure BiFeO3 Nanopowders Using Triethanolamine and Their Applications as Visible-Light Photocatalysts [J].
Cho, Chin Moo ;
Noh, Jun Hong ;
Cho, In-Sun ;
An, Jae-Sul ;
Hong, Kug Sun ;
Kim, Jin Young .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (11) :3753-3755
[5]   Multiferroic and magnetoelectric materials [J].
Eerenstein, W. ;
Mathur, N. D. ;
Scott, J. F. .
NATURE, 2006, 442 (7104) :759-765
[6]   Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route [J].
Ghosh, S ;
Dasgupta, S ;
Sen, A ;
Maiti, HS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (05) :1349-1352
[7]   Tunable synthesis of bismuth ferrites with various morphologies [J].
Han, Jan-Tao ;
Huang, Yun-Hui ;
Wu, Xiao-Jing ;
Wu, Chang-Liang ;
Wei, Wei ;
Peng, Bo ;
Huang, Wei ;
Goodenough, John B. .
ADVANCED MATERIALS, 2006, 18 (16) :2145-+
[8]   Synthesis and characterization of multifermic BiFeO3 powders fabricated by hydrothermal method [J].
Han, Seung Ho ;
Kim, Kyoung Sun ;
Kim, Ho Gi ;
Lee, Hyeung-Gyu ;
Kang, Hyung-Won ;
Kim, Jeong Seog ;
Cheon, Chae Il .
CERAMICS INTERNATIONAL, 2010, 36 (04) :1365-1372
[9]   X-RAY DIFFRACTOMETRIC DETERMINATION OF CURIE TEMPERATURE AND TEMPERATURE DEPENDENCE OF SPONTANEOUS POLARIZATION OF HEXAGONAL (RHOMBOHEDRAL) FERROELECTRICS [J].
ISMAILZADE, IG .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1971, 46 (01) :K39-+
[10]   Effects of Nb-doping on electric and magnetic properties in multi-ferroic BiFeO3 ceramics [J].
Jun, YK ;
Moon, WT ;
Chang, CM ;
Kim, HS ;
Ryu, HS ;
Kim, JW ;
Kim, KH ;
Hong, SH .
SOLID STATE COMMUNICATIONS, 2005, 135 (1-2) :133-137