(2,3,5,10,12,13,15,20-Octaphenyl-porphinato)copper(II) 1,1,2,2-tetrachloroethane solvate

被引：4
|
作者：
Bhyrappa, Puttaiah [1 ]
Karunanithi, Karuppaiah [1 ]
Varghese, Babu [2 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
[2] Indian Inst Technol, Sophisticated Analyt Instrument Facil, Madras 600036, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808000147
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Cu(C68H44N4)]·C2H2Cl4, exhibits nearly square-planar geometry around the CuII centre and the macrocyclic ring is almost planar. The porphyrin mol-ecule has an approximate non-crystallographic inversion centre (Ci ), and a non-crystallographic twofold rotation axis (C 2) within the CuII-porphyrin ring plane. Further, it has non-crystallographic twofold rotation axis and mirror plane (Cs ) symmetry perpendicular to the mol-ecular plane. The mol-ecular packing of the complexes and the solvent molecules shows weak inter-molecular C - H⋯π, C - H⋯Cl and C - H⋯N inter-actions, forming a clathrate-like structure.
引用
收藏
页码：M330 / U556
页数：20
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