Di-μ-diphenylphosphido-bis[tricarbonyliron(II)] dichloromethane solvate

被引：2

作者：

Ballinas-López, MG

Padilla-Martínez, II

Martínez-Martínez, FJ

Höpfl, H

García-Báez, EV

机构：

[1] Inst Politecn Nacl, Unidad Profes Interdisciplinaria Biotecnol, Mexico City 07340, DF, Mexico

[2] Univ Colima, Fac Ciencias Quim, Coquimatlan 28400, Colima, Mexico

[3] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca, Morelos, Mexico

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805020982

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the crystal structure of the title compound, [Fe-2(C12H10P)(2)-( CO)(6)]center dot CH2Cl2, the complex molecule lies across a mirror plane. Two diphosphide ligands bridge two (CO)(3)Fe fragments to form a dinuclear complex, in which the Fe-Fe distance is 2.6701 (6) angstrom. Two aromatic rings within the same molecule interact by face-to-face pi-pi stacking, with a centroid-to-centroid distance of 3.601 (2) angstrom.

引用

页码：M1475 / M1477

页数：3

共 6 条

[1]

BRUKER, 2000, SMART SAINT SHELXTL

[2] METAL PROMOTED ALKYL MIGRATION IN A BIMETALLIC COMPLEX [J].