Study on the Performance of Zn,N/TiO2 Anode Film and Co-Sensitization in DSSC

被引：15
作者：
Zhang, Jingchang [1 ,2 ]
Fu, Chengyu [1 ,3 ]
Yang, Xiuying [2 ]
Cao, Weiliang [1 ,2 ]
机构：
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Inst Modern Catalysis, Beijing 100029, Peoples R China
[2] Hainan Inst Sci & Technol, Haikou 571126, Peoples R China
[3] BOE Technol Grp Co Ltd, Beijing 100029, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2011年 / 21卷 / 01期
基金：
国家高技术研究发展计划(863计划);
关键词：
Zn; N doped-TiO2 film; Poly (3-dodecylthiophene); N719; P3DDT co-sensitization; DSSC; TIO2; SOLAR-CELLS; PHOTOELECTRIC CONVERSION PROPERTIES; HIGH-EFFICIENCY; ORGANIC-DYES; HEMICYANINE DYES; COUMARIN DYES; ELECTRODE; POLYTHIOPHENE; ENHANCEMENT; SUNLIGHT;
D O I：
10.1007/s10904-010-9416-z
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Zn,N-TiO2 powder was prepared using TiCl4 as the precursor. XRD, TEM and CV characterizations show Zn,N have been doped into nano-crystal TiO2 successfully, and the absorbance range of TiO2 anode red-shift to the visible region. Zn,N doped-TiO2 anode film was first prepared by combined technology. Ultraviolet-Visible (UV-Vis) chararterization proved there is a complementarity in UV-Vis absorbance range between poly (3-dodecylthiophene) (P3DDT) and N719. Solar cell based on Zn,N-TiO2 was first co-sensitized by P3DDT and N719. A solar-to-electric energy conversion efficiency of 3.25% was attained with the system. The photoelectric conversion efficiency, V-oc and J(sc) have been all increased compare to the single dye-sensitized solar cell.
引用
收藏
页码：43 / 49
页数：7
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