Fabrication and characterization of metal-supported solid oxide fuel cells

被引:47
作者
Lee, Changbo [1 ]
Bae, Joongmyeon [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mech Engn, Taejon 305701, South Korea
关键词
metal-supported solid oxide fuel cells; cathode; joining process; oxygen reduction reaction; in situ sintering; power density;
D O I
10.1016/j.jpowsour.2007.10.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal-supported solid oxide fuel cells (SOFCs) are an acceptable approach to solving the serious problems of SOFC technology, such as sealing and mechanical strength. In this work, commercial stainless-steel plates, STS430, are used as supporting bodies for a metal-supported SOFC in order to decrease the number of fabrication steps. The metal support for a single-cell has a diameter of 28 mm, a thickness of 1 mm, and a channel width of 0.4 mm. A thin ceramic layer, composed of yttria-stabilized zirconia (YSZ) and NiO/YSZ, is attached to the metal support by using a cermet adhesive. La0.8Sr0.2Co0.4Mn0.6O3 perovskite oxide serves as the cathode material because of its low impedance on the YSZ electrolyte, according to half-cell tests. The maximum power density of the cell is 0.09 W cm(-2) at 800 degrees C. The effects of temperature, oxygen partial pressure, and current collection by pastes are investigated. The oxygen reduction reaction at the cathode dominates the overall cell performance, according to experimental and numerical analyses. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:62 / 69
页数:8
相关论文
共 25 条
[1]   Electrochemical model for performance analysis of a tubular SOFC [J].
Akkaya, Ali Volkan .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2007, 31 (01) :79-98
[2]   Properties of La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) double layer cathodes on gadolinium-doped cerium oxide (CGO) electrolytes -: I.: Role of SiO2 [J].
Bae, JM ;
Steele, BCH .
SOLID STATE IONICS, 1998, 106 (3-4) :247-253
[3]  
Baker A., 2005, P FUEL CELL SEM PROG, P49
[4]   Strong performance improvement of La0.6Sr0.4Co0.8Fe0.2O3-δSOFC cathodes by electrochemical activation [J].
Baumann, FS ;
Fleig, J ;
Konuma, M ;
Starke, U ;
Habermeier, HU ;
Maier, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (10) :A2074-A2079
[5]   Development of metal supported solid oxide fuel cells for operation at 500-600 °C [J].
Brandon, NP ;
Corcoran, D ;
Cummins, D ;
Duckett, A ;
El-Khoury, K ;
Haigh, D ;
Leah, R ;
Lewis, G ;
Maynard, N ;
McColm, T ;
Trezona, R ;
Selcuk, A ;
Schmidt, M .
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2004, 13 (03) :253-256
[6]   Comparison of finite volume SOFC models for the simulation of a planar cell geometry [J].
Campanari, S ;
Iora, P .
FUEL CELLS, 2005, 5 (01) :34-51
[7]   Definition and sensitivity analysis of a finite volume SOFC model for a tubular cell geometry [J].
Campanari, S ;
Iora, P .
JOURNAL OF POWER SOURCES, 2004, 132 (1-2) :113-126
[8]   A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness [J].
Chan, SH ;
Khor, KA ;
Xia, ZT .
JOURNAL OF POWER SOURCES, 2001, 93 (1-2) :130-140
[9]   Electrochemical model of the integrated planar solid oxide fuel cell (IP-SOFC) [J].
Costamagna, P ;
Selimovic, A ;
Del Borghi, M ;
Agnew, G .
CHEMICAL ENGINEERING JOURNAL, 2004, 102 (01) :61-69
[10]   Electrode activation of anode-supported SOFCs with LSM- or LSCF-type cathodes [J].
Haanappel, V. A. C. ;
Mai, A. ;
Mertens, J. .
SOLID STATE IONICS, 2006, 177 (19-25) :2033-2037