Temperature-Dependence of an Amorphous Organic Thin Film Polariton Laser

Since its first observation, the polariton lasing threshold in organic films has been anomalously high, given that Bosonic condensation should occur at vanishingly small pumping powers. Here, we investigate the temperature dependence of a polariton laser employing an amorphous organic thin film, 2,7-bis[9,9-di(4- methylphenyl)-fluoren-2-yl]-9,9-di(4- methylphenyl)fluorene, in a vertical optical microcavity. An increase in laser threshold is observed at temperatures <45 K, while the threshold remains unchanged as the temperature increases up to room temperature. In contrast, the energy dispersion characteristic of cavity polaritons is independent of temperature. At low temperature, an energy relaxation bottleneck along the polariton dispersion takes place below threshold. The bottleneck is found to be responsible for the anomalous increase in threshold with decreasing temperature. As the pumping power increases, amplified spontaneous emission (ASE) is observed prior to the onset of lasing. We also study the photoluminescence of the neat organic film versus temperature to explain the origin of the bottleneck in the exciton polariton dispersion.