Challenges and perspectives of NASICON-type solid electrolytes for all-solid-state lithium batteries

被引：198

作者：

Hou, Minjie ^{[1
]}

Liang, Feng ^{[1
,2
]}

Chen, Kunfeng ^{[3
]}

Dai, Yongnian ^{[1
,2
]}

Xue, Dongfeng ^{[3
]}

机构：

[1] Kunming Univ Sci & Technol, Natl Engn Lab Vacuum Met, Kunming 650093, Yunnan, Peoples R China

[2] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Yunnan, Peoples R China

[3] Chinese Acad Sci, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

来源：

NANOTECHNOLOGY | 2020年 / 31卷 / 13期

基金：

中国国家自然科学基金;

关键词：

NASICON-type solid electrolyte; all-solid-state lithium-ion batteries; ionic conductivity; interface engineering; CARBON NANOMATERIAL PRODUCTION; ALUMINUM-TITANIUM PHOSPHATE; CERAMIC MEMBRANE SUPPORTS; CURRENT ARC-DISCHARGE; IONIC-CONDUCTIVITY; ELECTROCHEMICAL PROPERTIES; COMPOSITE ELECTROLYTE; ELECTRICAL-PROPERTIES; POLYMER ELECTROLYTE; GLASS-CERAMICS;

D O I：

10.1088/1361-6528/ab5be7

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

NASICON-type (lithium super ionic conductor) solid electrolyte is of great interest because of its high ionic conductivity, wide potential window, and good chemical stability. In this paper, the key problems and challenges of NASICON-type solid electrolyte are described from the aspects of ionic conductivity, electrode interface, and electrochemical stability. Firstly, the migration mechanism of lithium ion is analyzed from the three-dimensional structure of NASICON-type solid electrolyte, and progress in the research of conductivity and stability is summarized. Then, the effective methods to reduce interface impedance and improve the cycle stability of all-solid-state lithium batteries (ASSLBs) with NASICON-type solid electrolyte are introduced. Finally, solutions to improve the conductivity of electrolytes and deal with electrode/electrolyte interface problems are summarized, and the development prospects of ASSLBs are discussed.

引用

页数：16

共 167 条

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