Synthesis and characterization of an iron(II) η2-hydrazine complex

被引：64

作者：

Crossland, Justin L. ^{[1
]}

Zakharov, Lev N. ^{[1
]}

Tyler, David R. ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 25期

关键词：

D O I：

10.1021/ic702007r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron phosphine complex cis-[Fe(DMeOPrPE)(2)(eta(2)-N2H4)][BPh4](2) {DMeOPrPE = 1,2-bis[bis(methoxypropyl)phosphino]ethane} was synthesized and structurally characterized. The structure exhibits the first eta(2) coordination of hydrazine to iron, which may be relevant to intermediates trapped during nitrogenase turnover. The reaction of I with acid results in the formation of ammonia via a disproportionation reaction.

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页码：10476 / 10478

页数：3

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