Partial melting during exhumation of Paleozoic retrograde eclogite in North Qaidam, western China

Ultrahigh pressure (UHP) rocks are often overprinted by high pressure (HP) granulite-facies metamorphism during exhumation. Here we investigate retrograde eclogite from the Lvliangshan area in North Qaidam which is associated with abundant felsic veins. The eclogite adjacent to the vein shows conversion to garnet amphibolite. Petrographic, mineralogical, geochemical, geochronological data suggest that the eclogite has been experienced peak eclogite fades metamorphism at c. 440 Ma, followed by granulite facies retrogression at c. 420 Ma, and amphibolite facies overprinting at < 420 Ma. The retrograde eclogite has microstructural records for partial melting with elongated plagioclase grains occurring as veinlets along the garnet-ilmenite grain boundaries and interspersed in clinopyroxene. Moreover, highly cuspate, wedge shaped and triangular plagioclase grains are distributed along the garnet boundaries, and banded felsic veins (P1 + Qz) occur along the boundaries of amphibole in garnet amphibolite. Whole-rock geochemistry suggests that the felsic veins have 438.1-1106 ppm Sr and 2.87-12.18 ppm Y with Sr/Y ratios from 81.98-166.2, exhibit pronounced positive Eu anomaly, and depletion of HREE, resembling those of adakitic rocks. Felsic veins contain zircon grains with an U-Pb age of 422 Ma, similar to the age of HP granulite facies metamorphism (420 Ma) of retrograde eclogite. Combined with the identical Hf isotope compositions between the granulite facies zircon grains from the host retrograde eclogite and those from the felsic vein, we infer closed system partial melting during HP granulite fades retrogression of the retrograde eclogite. The tonalitic (high Sr/Y ratio and enrichment of LREE) chemical feature, low Rb/Sr and high Ba/Rb ratios of the felsic veins suggest that zoisite and sodic amphibolite dehydration melting together account for the formation of felsic veins during exhumation from the eclogite facies to granulite facies stages.